Calcium levels in aquarium
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URL: http://www.utahreefs.com/forum/forum_posts.asp?TID=2980
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Topic: Calcium levels in aquarium
Posted By: BigBlue
Subject: Calcium levels in aquarium
Date Posted: July 14 2004 at 4:28pm
I have relatively new (one month old) reef aquarium setup and
have been using RO water to replace evaporated water. I'm
losing about 1.25 gallons per day from a 72 gallon aquarium
(not including volume of about 12 gallons in sump).
I intend to start using Kalkwasser for top off. I read somewhere
that this is simply calcium hydroxide in solution. Can someone
please tell me what the final concentration of Calcium
Hydroxide should be in the top off water for my size aquarium
or does one need to measure uptake rates etc. before figuring
this out ? I expect a correction for true volume is required to
take account of live rock etc. ? Is there any toxicity associated
with too much calcium ? as long as pH is maintained ?
When I've learned enough about this subject I will consider a
calcium reactor but I'm obviously not ready yet.
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Replies:
Posted By: jfinch
Date Posted: July 14 2004 at 5:55pm
Saturated kalkwasser (or limewater) contains about 40 meq/l alkalinity and 800 ppm calcium with a pH over 12. How much your tank needs is something you will figure out as you go. Some people use saturated kalkwasser for all their make-up water. Some use less then that and others mix up an undersaturated solution. The only limits to kalkwasser usage is your tank water evaporation and pH.
As far as I know there is no toxicity associated with to high calcium. But there are water chemisty reasons to not do it. You will not be able to keep your alkalinity levels up with really high calcium levels. I would suggest targeting calcium levels at 350 to 450 ppm and alk levels at 2.5 to 4.
------------- Jon
https://www.youtube.com/channel/UC6y_EzjI_ljbIwf2n5uNzTw" rel="nofollow - What I've been doing...
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Posted By: BigBlue
Date Posted: July 14 2004 at 6:09pm
Jon,
By "saturated" do you mean keep adding Calcium Hydoxide to
the water used for top off until no more goes into solution ? That
would be a very high molar concentration of Calcium Hydoxide
and intuitively sounds like it might be toxic. Can you please
clarify.
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Posted By: jfinch
Date Posted: July 14 2004 at 6:38pm
By "saturated" do you mean keep adding Calcium Hydoxide to the water used for top off until no more goes into solution ?
Yes. What I (and many others) do is just dump lots of power in my container, add water and stir. The excess kalk will settle to the bottom. When the kalk solution is gone add more water and stir again. This can go on until the solids are gone. But if you use tap water (or let CO2 get into your solution) you will get CaCO3 solid precipitation. This will not dissolve and weakens the strength of the solution.
That would be a very high molar concentration of Calcium Hydoxide and intuitively sounds like it might be toxic.
Kalkwasser, Ca(OH)2, is not all that soluble. Just 1.5 to 2 teaspoons will saturate a gallon of water. If dosed too fast your tank pH can go too high which can be a problem. Most people dose slowly for this reason.
------------- Jon
https://www.youtube.com/channel/UC6y_EzjI_ljbIwf2n5uNzTw" rel="nofollow - What I've been doing...
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Posted By: coreyk
Date Posted: July 14 2004 at 6:45pm
i wanted to jump in for a little clarification for myself --- jon, are you saying that if you push your calcium levels to high with kalkwasser that your alk may crash?
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Posted By: reptoreef
Date Posted: July 14 2004 at 6:50pm
I am now using a kalk/ro mix for make-up water(fed via gravity controlled by float valve in sump (next to return pump) and have a ca reactor(affluent fed in at 1st chamber of sump, near chaeto and caulerpa) w/ph controller set at 8.3... all seems stable, at this point at morn:8.2 and eve:8.3. Looking for an ultimate constant level of 8.3. I mix the kalk/ro water in 55 gal bucket(DIY Kalk reactor) with a small powerhead at about midnight and 7 am to saturate while ph is at it's lowest levels.
------------- www.captivereefing.com
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Posted By: reptoreef
Date Posted: July 14 2004 at 6:52pm
BTW... last test results were Ca 430 Alk, 10 dkh, and mag 1350... Temp is 78 and sg is 1.024-1.025.
------------- www.captivereefing.com
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Posted By: coreyk
Date Posted: July 14 2004 at 6:56pm
reptoreef: just wondering what the advantage of both kalkwasser and a calcuim reactor is ?
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Posted By: ssilcox
Date Posted: July 14 2004 at 7:03pm
Kalkwasser can help push up your pH
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Posted By: imaexpat2
Date Posted: July 14 2004 at 7:27pm
I wouldnt use straight up 1.5 gallons of Kalkwasser soulution as my make up water...if thats what you were asking.
I have to add about 3 gallons of fresh water for make up water daily to my 135 SPS and Clam tank. I just drip about 3 qts of Kalkwasser solution via a dripper at a very slow rate during the night. That works really great for me keeping levels in the 450-500 range and PH in the 8.4 range consistantly
HTH's?
------------- 300 gal. Frag System
300 gal. Live Rock Vat
240 gal. SPS/Clam Reef Tank
135 gal. SPS/Clam Reef Tank
75 gal. Softies only Tank
65 gal. LPS/Softies
24 gal. SPS/Softies Nano Reef
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Posted By: Travis
Date Posted: July 14 2004 at 7:38pm
If the calcium and alkalinity is raised to high in the tank by anything it can cause precipition causing a lose of alk/ca/mag. http://www.utahreefs.com/forum/forum_posts.asp?TID=2208&KW=travis - http://www.utahreefs.com/forum/forum_posts.asp?TID=2208& KW=travis .
Kalk is great stuff... you just have to respect it.
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Posted By: jfinch
Date Posted: July 14 2004 at 9:09pm
Coreyk, I think your questions have been answered but I'll summarize.
High calcium levels can crash your alk. High alk levels can crash both your alk and calcium. And the main reason people dose kalk along with a reactor is for pH control. The reactor tends to depress pH (due to the CO2 in the effluent) and kalk tends to raise pH. And heed Imaexpat2 and Travis's caution regarding dosing kalk. Do it slow and keep an eye on your pH.
Kalk is one of the cheapest "balanced" calcium/alkalinity additives, but also one of the most difficult for many people to use.
------------- Jon
https://www.youtube.com/channel/UC6y_EzjI_ljbIwf2n5uNzTw" rel="nofollow - What I've been doing...
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Posted By: Mark Peterson
Date Posted: July 14 2004 at 10:40pm
Big Blue,
First, If you are coming to the meeting, I will give you a WMAS membership card there but be sure to ask me for it. If you don't make it to the meeting, PM me to mail it to you.
Second, I strongly recommend not using Kalkwasser for a while. Your tank is too young and immature to need it and it may cause more harm than good.
Perhaps you said this previously and I missed it, but why do you want to start using Kalwasser? Is it possible that you have $200+ of SPS and/or clams in the month old aquarium? Chemicals will cause problems unless you already understand these parameters and have been testing Calcium, Alkalinity/Hardness and pH factors for a few months.
I assume that you used an aragonite substrate in the tank. If not, please tell us what you used and we will advise.
------------- Reefkeeping Tips, & quick, easy setup tricks: www.utahreefs.com/forum/forum_posts.asp?TID=9244 Pay it forward - become a paid WMAS member
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Posted By: BigBlue
Date Posted: July 15 2004 at 12:41am
Mark,
Yes, I will be at the meeting tomorrow and will catch up with
you.
Regarding the tank, I did use an aragonite substrate (Carib Sea
Aragonite and some crushed coral) and luckily I only had four
SPS frags. Two of those croaked suddenly after I purchased
my own RO unit and started doing large water changes (more
on that in a couple days) and the other two don't look that great
since. Everything else in the tank are softies and they are
almost all doing very well although the Xenia is not growing
like a weed as described by others I have two green chromis
and one yellowhead jawfish. Everything was added very
slowly and the tank is pretty empty relative to what most people
have. The tank was cycled for about four weeks with live rock
before adding a few corals about six weeks ago so its really
about two months old. I thought that perhaps calcium was the
limiting factor for the SPSs so I was going to try Calcium
Hydroxide. I realize that eventually I'll have to get deeper into
water chemistry but I'm trying to take it one step at a time.
BB
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Posted By: Travis
Date Posted: July 15 2004 at 5:13am
A large part of dripping kalk or adding any additive is testing. If you do not already have test kits I would recommend getting Salifert Calcium, Alkalinity and Magnesium. IMO testing is what determines calcium/alk needs, not age, number of corals, etc. Most corals use ca/alk so not just sps or clam tanks require supplementing calcium/alkalinity.
With the sps corals, I would slow down a bit. They need a mature system, IMO not under 6-months old tank. They also need a very stable environment low in nutrients... which new tanks are usually not.
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Posted By: jfinch
Date Posted: July 15 2004 at 7:34am
Second, I strongly recommend not using Kalkwasser for a while.
For a beginner, B-ionic is a much safer choice.
A large part of dripping kalk or adding any additive is testing.
YES! If you regularly test while adding calcium and carbonates to your water you'll significantly reduce the potential for problems.
------------- Jon
https://www.youtube.com/channel/UC6y_EzjI_ljbIwf2n5uNzTw" rel="nofollow - What I've been doing...
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Posted By: BigBlue
Date Posted: July 15 2004 at 9:59am
Thanks for the advice everyone. See you tonight at the
stampede.
BB.
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Posted By: Mark Peterson
Date Posted: July 15 2004 at 10:55am
Travis wrote:
IMO testing is what determines calcium/alk needs, not age, number of corals, etc. |
Of course that is totally correct, Travis.
My strong recomendation to him not to use anything at this stage of the game, is based on my experience with newbies screwing everything up by adding chemicals, including b-ionic, when they don't even have a track record of coral growth and water parameters to go on. IME when the proper substrate and some LR is used, the tank does best if left to it's own ecology for at least the first four months.
All newbies should do water testing until they get the hang of the "look" of the tank.
Does this make sense/ do you agree?
------------- Reefkeeping Tips, & quick, easy setup tricks: www.utahreefs.com/forum/forum_posts.asp?TID=9244 Pay it forward - become a paid WMAS member
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Posted By: Travis
Date Posted: July 15 2004 at 7:36pm
All newbies should do water testing until they get the hang of the "look" of the tank.
No , you need to teach me the method of visually determining water parameters... it would some me a lot of time and money.
Fully agree, especially if one is not testing.
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Posted By: Mark Peterson
Date Posted: July 16 2004 at 8:11am
Maybe someone else would like to jump in here too. And maybe you know what I'm talking about and I can't see the teasing, I don't know But I will assume that you are serious and attempt to describe what I mean by "the look".
It's the school of experience that teaches this ability. When I see an aquarium I look for several things initially, like water color and clarity. (Crystal clear water is not what I look for, btw.) I observe the condition of all the algae especially if there is bright coralline algae, not covered over with softer algae.
Are the coral expanded or shrunken in?
Are the individual polyps fully extended or only partway out?
Do the edges of the coral, especially mushrooms, look burned/white and crinkled?
Is the color right for that coral.
Do the fish seem to be acting healthy or do they appear either sedated or else too active, hiding too quickly upon my approach.
Is there ample water circulation, especially at the surface.
Again, experience is the best teacher of these sometimes subtle conditions.
Also, the smell of a tank is an indicator. A person from the coast of New Zealand was at my home a few years ago. He commented that my tank smelled just like the ocean!
I was helping SMatney with her new, but previously owned, tank the other day. I casually leaned over to smell it. She noticed my move and waited... "This has been a FO tank," I commented. Coral reef tanks have a particular smell. And each one can smell slightly different depending on the mix of coral and filtration methods.
Before anyone gets the idea that I'm setting myself above as some kind of guru, I'm not, but when you've seen as many tanks as I have, you've seen coral at their worst and at their best. Recognizing when they are starting to struggle should be the goal of serious hobbyists, IMO.
Here is the best advice I ever received from a book:
As you daily walk past the tank, try to observe it's general condition. Note any changes from the previous day/week/month. Growth is a very good positive sign, whereas the lack of it most always signals a problem.
I saw Jamison's tank a couple months ago. He pointed out his concern with a receding Frogspawn. I observed that the water current went past a large anemone then hit the Frogspawn, which was about six inches away. We changed the water current by shifting piping, which was also intended to improve pH, and then moved the Frogspawn to the other side of the tank. Jamison told me last night at the meeting, that the coral lost a couple heads, most likely due to exposure to the anemone, but the heads that remain are doing well. He then commented that he still has a problem with algae. I mentioned that he may need to consider more snails and hermits. He embarrassingly nodded in acknowledgment, admitting that he hadn't added more as I had suggested back then.
We live and learn
------------- Reefkeeping Tips, & quick, easy setup tricks: www.utahreefs.com/forum/forum_posts.asp?TID=9244 Pay it forward - become a paid WMAS member
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Posted By: jfinch
Date Posted: July 16 2004 at 9:07am
Anyone can learn to test their water. It's not very difficult or expensive. The experienced eye can see when a tank needs attention quicker then an inexperienced one, but it's always after the fact. It's just too darn easy to maintain calcium and alkalinity through testing and dosing, which is why I will always recommend it. As for the myriad of other additives... I would exercise more caution and maybe lean more to the eye of experience.
------------- Jon
https://www.youtube.com/channel/UC6y_EzjI_ljbIwf2n5uNzTw" rel="nofollow - What I've been doing...
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Posted By: coreyk
Date Posted: July 16 2004 at 12:16pm
how often do you guys test your ca, alk, and mag?
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Posted By: reptoreef
Date Posted: July 16 2004 at 12:28pm
Ca and alk seem to be the most quickly depleted... Do you have a lot of sps or clams? Test your Ca regularly until stable(dose if neccessary). Alk is a big factor in maintaining the PH of the bulk water. If ph drops, chances are that Alk is low( again, test and dose as neccessary, testing less frequently as stability is maintained). As for mag, I tested for my first time in 5 years, last week and it was at 1350(perfect)... I have been given the impression that so long as your doing regular water changes, your mag levels should naturally maintain well. If not, test then dose accordingly.
------------- www.captivereefing.com
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Posted By: jfinch
Date Posted: July 16 2004 at 12:42pm
I test my alk weekly, calcium monthly and Mg "less frequent" If I'm fiddling with my levels and changing my dosing regime I'll test every couple days.
------------- Jon
https://www.youtube.com/channel/UC6y_EzjI_ljbIwf2n5uNzTw" rel="nofollow - What I've been doing...
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Posted By: Weimers
Date Posted: July 16 2004 at 2:21pm
Jon,
Just checking for clarification - if I remember right, you test your Alk weekly (because it's a good and quick indicator of any problems). You personally don't need to test the calcium all the time, because you know that your alk is steady. Correct? If it was high or low, then you would test Calcium. Right?
Btw, my Alk is still tilted to the low side, but my calcium is steady. Your suggestions are great - it has really helped. Thanks!! But I have to admit that I sometimes wonder whether I should be looking toward a calcium reactor. Reptoreef sounded like he had a nifty calcium reactor. (Sorry - repto - I can't remember enough of the details to be more detailed. But I'll bet Jon would love it.)
Renee
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Posted By: Adam Blundell
Date Posted: July 16 2004 at 3:23pm
jfinch wrote:
I test my alk weekly, calcium monthly and Mg "less frequent" If I'm fiddling with my levels and changing my dosing regime I'll test every couple days. |
I don't think it would be possible for me to test "less frequently".
Adam
------------- Come to a meeting, they�re fun!
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Posted By: Mark Peterson
Date Posted: July 17 2004 at 6:52am
Adam and all,
Wouldn't you say that doing no testing whatsoever has a lot to do with your years of experience giving you the confidence to set up the tank in the right way from the start.
1. Using all Aragonite substrate of sufficient quantity and proper size.
2. Buying sufficient light, circulation and external filtration(skimmer, etc.) to make it all grow.
3. Then adding the right amount of LS, LR, LW and algae to get it going and keep it going.
4. And finally, inserting the right mix of organisms in the right order and quantity. (lots of coral first, followed by other inverts and more herbivorous rather than carnivorous fish)
Did I leave anything out?
Oh, and keeping a watchful eye on the janitor population so that algae is kept in check.
------------- Reefkeeping Tips, & quick, easy setup tricks: www.utahreefs.com/forum/forum_posts.asp?TID=9244 Pay it forward - become a paid WMAS member
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Posted By: Suzy
Date Posted: July 17 2004 at 8:05am
jfinch wrote:
I test my alk weekly, calcium monthly and Mg "less
frequent"� If I'm fiddling with my levels and changing my dosing
regime I'll test every couple days. |
When did you start testing for Mg+?? Mr Smarty pants!!!
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Posted By: Adam Blundell
Date Posted: July 17 2004 at 8:17am
Mark,
Yep I think you got it. Plus, I don't keep those lame corals that end in pora. You stony guys what is it that makes you like them? Nope, just green stars and polyps for me.
Adam
------------- Come to a meeting, they�re fun!
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Posted By: Travis
Date Posted: July 17 2004 at 4:28pm
I test ca/ alk weekly usually... magnesium every two to four weeks. I both my tanks the ca/ alk levels can drop pretty quick, the 110g has a ca reactor and I drip kalk so I monitor that regularly (usually get the same readings) and the 55g with mostly softies and some LPS corals and one sps coral but it has a more fluctuating ca/alk level than the 110g... I test it weekly and add ca/alk as needed (which it is needed twice a week) and test nitrates monthly. All the expeariance in the world wouldn't make my tanks take up any less ca/alk. Now if you never add additives I guess there would be no reason to test...
edit: forgot phosphates which I test for monthly... and PH often.
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Posted By: Travis
Date Posted: July 17 2004 at 4:35pm
Mark Peterson wrote:
Maybe someone else would like to jump in here too. And maybe you know what I'm talking about and I can't see the teasing, I don't know But I will assume that you are serious and attempt to describe what I mean by "the look". |
It would seem to me the "look" is healthy vs unhealthy?? I'm I right?? I test to keep from getting a unhealthy tank... preventive maintenance. I'm sure you're correct in your observations but at the point you can see signs of trouble, the tank is already in trouble.
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Posted By: Mark Peterson
Date Posted: July 18 2004 at 9:14am
Well, Yes, ...and No.
First, the reason for my "No"
There really are subtle changes that occur before problems emerge. In my own tanks, I try to notice those subtle changes, though sometimes a problem emerges and I think back and realize that I saw the subtle change, but failed to act.
And second, Yes in tanks that I visit just once or twice, I cannot see subtle changes for obvious reasons. As Travis said, "...the tank is already in trouble." That's usually why I'm there.
I'm pretty sure that you too are learning to notice those subtle changes on your own tank(s), and yet only when you stop to think about it do you become aware of the gift of this developing ability.
Perhaps I should explain. Even though I don't test much or often, I do believe that testing is important.
When we listen to someone tell us about their tank's problems, one of the things we want to know is their testing results. This is a way for them to communicate something of the tanks' condition, without actually examining the tank. And often, as is the case here on the MB, this and other info can lead us to a good diagnosis and effective solution, having never "seen" (or smelled ) their aquarium.
$0.02 x 2000+ posts, that's over $20 of advice I've contributed to this MB
------------- Reefkeeping Tips, & quick, easy setup tricks: www.utahreefs.com/forum/forum_posts.asp?TID=9244 Pay it forward - become a paid WMAS member
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Posted By: Adam Blundell
Date Posted: July 18 2004 at 4:03pm
Mark Peterson wrote:
When we listen to someone tell us about their tank's problems, one of the things we want to know is their testing results. This is a way for them to communicate something of the tanks' condition, without actually examining the tank. And often, as is the case here on the MB, this and other info can lead us to a good diagnosis and effective solution, having never "seen" (or smelled ) their aquarium.
$0.02 x 2000+ posts, that's over $20 of advice I've contributed to this MB  |
I actually don't care what there testing results are. Maybe I should. Usually I think people are including that info for Mark, and I just skip right over it. I usually care about how much rock, corals, fish, and light are in the tank.
Also, Mark's $.02 x 2000 would be $40
Adam
------------- Come to a meeting, they�re fun!
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Posted By: Mark Peterson
Date Posted: July 18 2004 at 7:18pm
If my advice is like my math skills, I'm in trouble
------------- Reefkeeping Tips, & quick, easy setup tricks: www.utahreefs.com/forum/forum_posts.asp?TID=9244 Pay it forward - become a paid WMAS member
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Posted By: jfinch
Date Posted: July 18 2004 at 9:23pm
Just checking for clarification - if I remember right, you test your Alk weekly (because it's a good and quick indicator of any problems). You personally don't need to test the calcium all the time, because you know that your alk is steady. Correct? If it was high or low, then you would test Calcium. Right?
I check alk more frequently then calcium because it will vary more then calcium. And if you're using a balanced calcium/alkalinity additive (CO2/CaCO3 reactor, kalkwasser, b-ionic) then you're adding both in the same proportion that they are most likely being consumed (so yes if alk is fine, calcium will be fine too). For every 1 meq/l of alkalinity consumed through calcification there will only be 20 ppm of calcium depleted. If my aquarium is sitting at 3 meq/l and 430 ppm Ca and I stop adding supplements, within a week my alkalinity will drop down to 1.5 meq/l but my calcium will only drop to 400 ppm. An alk of 1.5 is stressful to calcifying corals, but a calcium level of 400 ppm is fine. That is why I check alkalinity more frequent then calcium.
When did you start testing for Mg+?? Mr Smarty pants!!!
I've always tested "less frequently" . I check Mg about once very two to three months. I've never tested low until just recently. Apparently my coralline is growing faster and consuming Mg faster then I'm adding it in my fish food and water changes.
Plus, I don't keep those lame corals that end in pora.
Hey if it weren't for those corals (and other calcifiers) you wouldn't have coral reefs as we know them. I'm just doing my part to acknowledge they're role 
If you don't add calcium and carbonates to a tank with calcifying corals you're most likely stressing them unduly. They need both to grow. I would dare to bet that neither Mark or Adam has kept a tank dominated with calcifying corals. If I neglect my tank (which I occasionally do ) my alk will drop down below 2 meq/l. The first sign is the growth edge on my plating montiporas lose their color. It doesn't take a real long time of low alk to cause this, maybe a week. And once the damage is done it takes a few weeks to get them back to full color and growth rates. Why should I wait until my montis start to lose their color before acting?
Adam and Mark... you know I love you guys, but I've got a feeling that we will aways be at opposite ends of this discussion.
------------- Jon
https://www.youtube.com/channel/UC6y_EzjI_ljbIwf2n5uNzTw" rel="nofollow - What I've been doing...
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