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DIY buffer

Printed From: Utah Reefs
Category: Specialized Discussion
Forum Name: DIY
Forum Description: Do it Yourself
URL: http://www.utahreefs.com/forum/forum_posts.asp?TID=6389
Printed Date: May 11 2025 at 5:43pm
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Topic: DIY buffer
Posted By: Shane H
Subject: DIY buffer
Date Posted: April 29 2005 at 7:24pm
So, Jon - I'm making up another batch of buffer and was wondering if you see any benefits to adding borate to the mix?
Are there any benefits?
Any downsides?
What ratio would you use if you think it should be added?
Would you just use the 20 Mule Team Borax?
Did we talk about this on the way to Boise?
Is this enough questions for one post?



Replies:
Posted By: nick
Date Posted: April 29 2005 at 7:30pm
Hey Shane,please if you don't mind me asking,what do you mean by making a batch of buffer.

-------------
The Eyes Of Texas Are Upon You.

Hook'em Horns.


Posted By: Shane H
Date Posted: April 29 2005 at 7:34pm
Rather than buying commercial buffer, I generally just make my own. I have been following Jon's recommended recipe of 5 parts baking soda to 1 part washing soda with great success. I add it occassionally, (or often lately) to increase alkalinity.
But, I was reading the ingredients on an empty container of Kents SuperBuffer dkH and saw that it contains borate salts. So, I'm wondering why they add this?


Posted By: bugzme
Date Posted: April 29 2005 at 7:53pm
That would be a great addition to the how to pamplets! Ive never heard of that.

-------------
Jeff
125 tank
50 gallon sump
T-5 lighting
Rum drinker, Carbon User
I KNOW ROCKS THAT ARE YOUNGER THEN ME!! I AM A Realist! I write what I think!!


Posted By: nick
Date Posted: April 29 2005 at 7:59pm

Thanks for the info Shane,like Jeff was saying it would be nice if this kind of information was on a pamphlet for new guys like us.



-------------
The Eyes Of Texas Are Upon You.

Hook'em Horns.


Posted By: jfinch
Date Posted: April 29 2005 at 10:45pm

I do not suggest adding any borate (borax) to your buffer mix.  Seawater is only about 5 ppm boron and is not really consumed in reef tanks.  So, I think you will get enough from your saltmix.

Are there any benefits?

Yes, borate is a wonderful buffer.  Better then carbonates at keeping pH at 8.3.

Any downsides?

Yes.  Since it is not readily consumed in your tank, it will slowly accumulate.  Borates are included when you test for alkalinity.  Normally, borates only account for about 3% of your total alkalinty, so we just ignore it and assume all of our alkalinity is due to carbonates (the good stuff that corals need).  But as it accumulates, more and more of your alkalinity measurement will be borates and not carbonates.  So you might think you have an alkalinity (due to carbonates) of 3 meq/l but in reality it might only be 1 meq/l carbonates and 2 meq/l borates.  Your corals will suffer due to the low carbonates.

The other issue is that at levels around 50 ppm it becomes toxic to some aquatic life.

Would you just use the 20 Mule Team Borax?

Yup, if I were to add borates, I'd use 20 Mule Team.

Did we talk about this on the way to Boise?

I don't think so.

Is this enough questions for one post?

I'm always game for more

...Kents SuperBuffer dkH and saw that it contains borate salts. So, I'm wondering why they add this?

They add it to help maintain pH, imo.  It likely contains a very very small amount.  But do not use Seachem Marine pH 8.3 Marine Buffer.  It contains HUGE amounts of borate and can raise havoc in a reef tank.  It's likely ok for a fish only though.

DIY Buffer for the new people :

5 parts baking soda
1 part washing soda (you can bake baking soda at 300F for 2 hrs to make washing soda)

It's as simple as that!



-------------
Jon

https://www.youtube.com/channel/UC6y_EzjI_ljbIwf2n5uNzTw" rel="nofollow - What I've been doing...



Posted By: Shane H
Date Posted: April 30 2005 at 10:46am
Jon,

Thanks for the info. I knew you knew.

Shane H


Posted By: Robudda
Date Posted: April 30 2005 at 11:08am
How much do you normally make? how long is it good for? And do you just add let's say a tsp of powder straight to the water, or add it to your water change water that sits for a day or 2? I see so many that say alkalinity should be 8-12dkh, but my test strips give my results in ppm (I will be upgarding testing equipment soon) but let's say my test strip has 180ppm is this Ok or does it need to be raised, and how much of this homemade buffer should be added?

example-1 tsp per gallon during water change will raise Alkalinity this much ppm or this much dkh.

Sorry still a newb but this sounds interesting (and would be a good topic in the Sw pamphlet they been talking about)

Rob


Posted By: jfinch
Date Posted: April 30 2005 at 2:15pm

how long is it good for?

A really long time.  Don't worry about it going bad.

And do you just add let's say a tsp of powder straight to the water, or add it to your water change water that sits for a day or 2?

Just add some to your make-up water, let it dissolve and then slowly pour it into your sump or tank.  The amount to be added depends on the size of your tank and your current alkalinity.

I see so many that say alkalinity should be 8-12dkh, but my test strips give my results in ppm (I will be upgarding testing equipment soon) but let's say my test strip has 180ppm is this Ok or does it need to be raised, and how much of this homemade buffer should be added?

There are three ways to describe alkalinity (kinda like there are two ways to describe temperature, degrees F and C):  meq/l, dKH and ppm CaCO3.  And

1 meq/l = 2.8 dKH = 50 ppm CaCO3

So your 180 ppm = 180/50*1 = 3.6 meq/l or

180/50*2.8 = 10.1 dKH

You're alkalinity is just fine (assuming those test strips work).



-------------
Jon

https://www.youtube.com/channel/UC6y_EzjI_ljbIwf2n5uNzTw" rel="nofollow - What I've been doing...



Posted By: Robudda
Date Posted: April 30 2005 at 3:03pm
Wow , thanks so much for the explanation and ppm to dkh conversion. That helps a lot.

I do not fully trust the test strips. The ammonia/Nitrite/Nitrate seems pretty stable, but does not show the accuracy (As in the in between numbers, it is frustarting to say it is lighter then this but darker then this with such a wide range) I would like, and PH and Alk seem to change from test strip to test strip. I will start to purchase a few of the most important Salifert tests a couple at a time.

Thanks again,
Rob


Posted By: bugzme
Date Posted: April 30 2005 at 3:40pm
I wouldn't put anything in my tanks without accurate test kits! Strips are not accurate IMO

-------------
Jeff
125 tank
50 gallon sump
T-5 lighting
Rum drinker, Carbon User
I KNOW ROCKS THAT ARE YOUNGER THEN ME!! I AM A Realist! I write what I think!!


Posted By: Xacttech
Date Posted: May 01 2005 at 11:16pm
So those of you who use Baking Soda/washing soda, what Calcium
additive do you use as your part B?

Also if you have been using B-ionic on your system for a few months, and
switch to the Homebrew system what is a good starting dose on a 95
gallon tank w/ 125 gallon gross system?


Posted By: jfinch
Date Posted: May 02 2005 at 12:01am

what Calcium additive do you use as your part B?

Kent's Turbo Calcium is the most common.  The DIY crowd uses Peladow or Dowflake (or Prestone Driveway Heat) calcium chloride ice melt.  Those are the only brands I would try.

Also if you have been using B-ionic on your system for a few months, and switch to the Homebrew system what is a good starting dose on a 95 gallon tank w/ 125 gallon gross system?

First off, I personally don't recommend using just baking soda and calcium chloride in place of B-ionic (although there are folks here that do and appear to be successful at it).  B-ionic also contains a bunch of other elements found in seawater that aren't in baking soda.  But as for how much to use... how much B-ionic are you using now?



-------------
Jon

https://www.youtube.com/channel/UC6y_EzjI_ljbIwf2n5uNzTw" rel="nofollow - What I've been doing...



Posted By: Xacttech
Date Posted: May 02 2005 at 10:05am
About 15 ml per day.

What other essentail elements does it add that I don't get from my weekly
5% water change, or as long as I keep up on the water changes will I be
okay to switch to DIY buffer?

Or is the B-ionic fully worth the $$ based on performance and benefits.

What are those who have a calcium reactor supposed to do to get those
elements that B-ionic add?

Thanks for all the help, sorry to hijack the thread


Posted By: jfinch
Date Posted: May 02 2005 at 11:19am

15 ml of B-ionic is equivalent to 3.5 g of baking soda (about 1 tsp) and 2.3 g of turbo calcium (just under a tsp).

What other essentail elements does it add that I don't get from my weekly 5% water change, or as long as I keep up on the water changes will I be okay to switch to DIY buffer?

If all you add is NaHCO3 and CaCl2 then over time as the CO3 and Ca are consumed by your coral, the remaining Na and Cl will accumulate.  This is what is refered to as "ionic imbalance".  B-ionic contains all the other elements found in seawater to "balance" out all the excess Na and Cl.

Or is the B-ionic fully worth the $$ based on performance and benefits.

*shrug*.  I really like B-ionic for a low-medium calcium demand tank, but you might want to speak to people using just baking soda and CaCl2 too.

What are those who have a calcium reactor supposed to do to get those elements that B-ionic add?

When you dissolve coral skeleton, you don't have those excess Cl and Na ions so an ionic imbalance doesn't occur.  And the idea is that whatever elements that were needed for coral skeleton growth will be dissolved in the reactor and added to the tank for new coral growth.



-------------
Jon

https://www.youtube.com/channel/UC6y_EzjI_ljbIwf2n5uNzTw" rel="nofollow - What I've been doing...



Posted By: Xacttech
Date Posted: May 02 2005 at 12:32pm
Okay, so what do you suggest...

I don't believe my tank is currently a high demanding calcium tank, only
10 or so SPS Frags, 2 LPS, 1 Clam, 120 gallon gross.

Oceanic Salt, 5-10 gallons weekly water change. Tap water Top off, RO
for changes.

Just looking for my best, most cost effective solution.


Posted By: jfinch
Date Posted: May 02 2005 at 12:35pm

Just looking for my best, most cost effective solution.

Kalkwasser every day with the occasional "boost" from baking soda and CaCl2 when/if needed. 



-------------
Jon

https://www.youtube.com/channel/UC6y_EzjI_ljbIwf2n5uNzTw" rel="nofollow - What I've been doing...



Posted By: Xacttech
Date Posted: May 02 2005 at 2:02pm
Thanks for the suggestion...

I don't like the idea of Kalkwasser however... not really for any good
reason other than it seams accidental over dose occurs with it more than
any other buffering agent. I'm a little bit scared from the horror stories
I've heard/wittnessed.

Is it your opinion that Kalkwasser is better than B-ionic, or just more cost
effective?

Maybe I'll give it a go, but I think I need a surefire dosing method that
won't cause ulcers


Posted By: jfinch
Date Posted: May 02 2005 at 2:28pm

Kalkwasser is definatly the most difficult additive to dose.  It's unforgiving.  You must watch your pH.  But it's not so difficult that you can't do it.

Is it your opinion that Kalkwasser is better than B-ionic, or just more cost effective?

Just more cost effective.  If cost was not an issue, I'd throw my kalkwasser and calcium reactor in the garbage and only use B-ionic!

Maybe I'll give it a go, but I think I need a surefire dosing method that
won't cause ulcers

If you're afraid to drip then how 'bout doing what Julian Spung does (and still suggests).  Add 1/8 - 1/2 tsp of kalk to 1 quart of RO water, stir it up and just dump it into your sump.  Do this every day just before going to bed (and maybe even every morning too).



-------------
Jon

https://www.youtube.com/channel/UC6y_EzjI_ljbIwf2n5uNzTw" rel="nofollow - What I've been doing...



Posted By: jfinch
Date Posted: May 02 2005 at 2:31pm

Oh I forgot...

Don't let me or anyone else pressure you into doing something you're not comfortable with.  There are many ways to maintain alk and calcium in a reef tank.  Chose one that you're comfortable with.



-------------
Jon

https://www.youtube.com/channel/UC6y_EzjI_ljbIwf2n5uNzTw" rel="nofollow - What I've been doing...



Posted By: Mark Peterson
Date Posted: May 02 2005 at 3:20pm
I would definitely not use any additives at all for a tank before it's reached 4 months of age. (Assuming the tank was set up with aragonite/calcium carbonate substrate and rock.) And then only tanks with a load of Ca using coral or clams should be worried about adding anything. 10-20% monthly water changes add all that is needed for 99% of new tanks.

Additionally, these chemical can cause big problems. I would track Alkalinity and Calcium leves for several weeks before beginning to add anything.

But don't let stories scare you. Study it out and do it right the first time. The gallon milk jug method with a pinhole is very safe, until the jug is perched where it can fall into the tank, spilling it's entire contents at once. Put a pinhole in the cap and screw it on tight. Then, even if it falls in, it won't cause a chemical problem.

-------------
Reefkeeping Tips, & quick, easy setup tricks:
www.utahreefs.com/forum/forum_posts.asp?TID=9244
Pay it forward - become a paid WMAS member


Posted By: Xacttech
Date Posted: May 02 2005 at 3:47pm
Thanks very much, I think I'll stick with B-ionic till my tank has a bigger
need for calcium, at which point I'll look into a reactor

My tank may only be a few months old, but my system is about 8 months
old. And even in my new tank I have corraline growth that's hard to keep
off the front side(s) of the acrylic.

I hope this thread helped out more people than just me because I think it
answered a lot of questions those of us novice people have needed.



Perhaps a sticky/FAQ based on this thread would be good.


Posted By: rstruhs
Date Posted: May 07 2005 at 12:59am
Originally posted by jfinch jfinch wrote:

Kalkwasser is definatly the most difficult additive to dose.  It's unforgiving.  You must watch your pH.  But it's not so difficult that you can't do it.

Is it your opinion that Kalkwasser is better than B-ionic, or just more cost effective?

Just more cost effective.  If cost was not an issue, I'd throw my kalkwasser and calcium reactor in the garbage and only use B-ionic!

Maybe I'll give it a go, but I think I need a surefire dosing method that
won't cause ulcers

If you're afraid to drip then how 'bout doing what Julian Spung does (and still suggests).  Add 1/8 - 1/2 tsp of kalk to 1 quart of RO water, stir it up and just dump it into your sump.  Do this every day just before going to bed (and maybe even every morning too).

Jon, I am trying to cost justify either a Kalkwasser or Calcium reactor versus the B-Ionic that I am currently using.  Can you help me justify one or the other or both?

TIA



-------------
Rodney, Sandra, Jeffery, and Laura Struhs
South Jordan, Utah 98th South & 40th West.
(801) 282-2744

75 gallon reef
55 gallon reef
55 gallon FOWLR
20 gallon FOWLR


Posted By: jfinch
Date Posted: May 07 2005 at 3:13pm

If we just look at the usage cost, here's what I come up with:

B-ionic (@$35 per 2 gallons - mail order pricing): $3.31 per 1000 meq of alkalinity

Kalkwasser (using cheap pickling lime):  $0.15 - $0.35 per 1000 meq

Calcium reactor (figuring $30 in CO2 and $20 in 15 lbs of substrate):  $0.37 per 1000 meq

If your tank is 100 gallons and it consumes 0.4 meq/l per day then you'll go through 55,188 meq of alk per yr. 

Using B-ionic that would cost: $183 per yr

Using kalkwasser:  $8.30 - $19.32 per yr

Using calcium reactor:  $20.42 per yr

So roughly speaking, for this hypothetical tank, you would save about $160 per yr by using either kalk or a reactor.  Or in other words, if you were to spend $400 on a calcium reactor it would pay for itself in about 2.5 yrs.  On the other hand, you can drip kalk without spending hardly anything on set-up so it'll start paying for itself from day one.



-------------
Jon

https://www.youtube.com/channel/UC6y_EzjI_ljbIwf2n5uNzTw" rel="nofollow - What I've been doing...



Posted By: Adam Blundell
Date Posted: May 07 2005 at 8:28pm

Jon-
That is excellent information.  Are you sure on those figures and may I quote you on them?

Adam



-------------
Come to a meeting, they�re fun!


Posted By: jfinch
Date Posted: May 07 2005 at 11:32pm

You can quote me on that.



-------------
Jon

https://www.youtube.com/channel/UC6y_EzjI_ljbIwf2n5uNzTw" rel="nofollow - What I've been doing...




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