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DIY Testing kit

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Keither View Drop Down
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    Posted: March 15 2004 at 10:13pm

I was shopping around looking for a master test kit whne it occured to me: "Why should I pay a bazzilion dollars when I (a man with almost a chem minor) could track down all the chemicals myself and save a bundle."

Then I asked myself(It was a late night, my wife was asleep, and the fish weren't answering), "I bet you if it could be done, it's been done on the forum and you should ask."

"Very sharp," I aswered back, "Let's post, it's free anway."

So, has anyone tried and/or done it?  What was your methodology?  I want the whole nine yards of a test kit, or maybe the first 3 I could save on.

-Keither

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jfinch View Drop Down
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Post Options Post Options   Thanks (0) Thanks(0)   Quote jfinch Quote  Post ReplyReply Direct Link To This Post Posted: March 15 2004 at 10:33pm

Who knew I would answer this question .

It's very easy to make an alkalinity "kit".  You're alk test is just an acid/base titration using a strong mineral acid.  I use H2SO4, 0.05 M.  I use methyl orange for indicator.  By definition alkalinity is a titration down to the bicarbonate-carbonic acid endpoint, which is pH=4.2.  Right as the methyl orange changes from yellow to orange is the endpoint.  If you have a pH meter you can just use it and stop the titration at 4.2.  If you don't have access to a mineral acid and methyl orange indicator, it's probalby cheaper to just buy a test kit .

The other test kits are, I believe, all based on EPA methods and can be found on the EPA website (somewhere, but I don't remember where).  They all require special indicator dyes/solutions so they're usually not a DIY kinda thing.

We can talk more if you want, I like this stuff

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Suzy View Drop Down
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Post Options Post Options   Thanks (0) Thanks(0)   Quote Suzy Quote  Post ReplyReply Direct Link To This Post Posted: March 16 2004 at 5:31am
Is there an expiration point on our test kits? I mean, when they get
"old" (less fresh?) , do they not work as well?

'Cause, how can chemicals get old?

Keither, if you go to the crafts store, they have these boxes for
cross stitching thread. They work great for storing all the test kit
parts! I used to use a fishing tackle box, 'till I got sick of cross
stitching!
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jfinch View Drop Down
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Post Options Post Options   Thanks (0) Thanks(0)   Quote jfinch Quote  Post ReplyReply Direct Link To This Post Posted: March 16 2004 at 6:28am
Suzy, some kits can get old.  I wouldn't worry too much about an alkalinity kit, but some of the other chemicals can react just sitting in the bottle and change composition causing errors in the measured reading.  For example, the chemicals used in the ammonia kit are very sensitive to UV and should be stored in a dark place (there's enought UV that sneaks through the plastic bottle to cause harm).  Heat also can cause harm.
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Jared Wood View Drop Down
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Post Options Post Options   Thanks (0) Thanks(0)   Quote Jared Wood Quote  Post ReplyReply Direct Link To This Post Posted: March 16 2004 at 8:50am

Doesn't Adam just use the Tang test?

If his wife's tangs start dying then something is wrong.  If they don't die then the water is fine.

In the beginning, God created the heaven and the earth ... then He let it cycle.

Have you read my dinosaur theory yet?
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Adam Blundell View Drop Down
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Post Options Post Options   Thanks (0) Thanks(0)   Quote Adam Blundell Quote  Post ReplyReply Direct Link To This Post Posted: March 16 2004 at 8:57am

Jared,

To a certain extent... that is correct.

Adam

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Post Options Post Options   Thanks (0) Thanks(0)   Quote Adam Blundell Quote  Post ReplyReply Direct Link To This Post Posted: March 16 2004 at 9:00am

Let me elaborate on what Jared brought up.  Think about it, if all your stuff is alive and doing well, do you really care what the test kits say?  Do you have reason to even test?
Second part.  If your fish are dying and your corals are bleaching wouldn't you do something, even if the test kits say everything is okay?  The levels may read perfect but not many people would say "oh well, I guess they are just dying, my levels look fine".

Adam

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Post Options Post Options   Thanks (0) Thanks(0)   Quote jfinch Quote  Post ReplyReply Direct Link To This Post Posted: March 16 2004 at 9:16am
Yes, but testing can keep you from ever getting to the point where your corals start dieing.  And if you want faster then normal growth, you better test, imo.
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Keither View Drop Down
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Post Options Post Options   Thanks (0) Thanks(0)   Quote Keither Quote  Post ReplyReply Direct Link To This Post Posted: March 16 2004 at 9:16am

I'm very into this stuff also, jfinch.  I'm attending the U in Biomedical Engineering, and I almost had a chem minor(one class away) but I got bored with Biochem.  I like applied physiology, not just biochem. O chem and Gen Chem were more interesting.

I understand the techniques, but is it viable to build one yourself?  I mean they only give you small bottles of everything, would it be a worthwhile venture to go and find some of the chems you need in somewhat larger quantities, instead of a couple of mils, I'd get a couple deci liters or something.  (I'm still stuck in a biggie size mentality --Maybe I should sue)

Thanks for the suggestion Suzy, I like it.  Now I need a kit :)  I was doing some Ebay scouting and found a master kit for 40-50 buck.  I'd like to start out with a master kit.  I've been doing fish for 3 years and never had a test kit.  I always used the plants and fish to tell me what was going on--and Petsmart's free testing :)

--Keither

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Post Options Post Options   Thanks (0) Thanks(0)   Quote Carl Quote  Post ReplyReply Direct Link To This Post Posted: March 16 2004 at 9:45am

Adam, I agree with you in part that testing isn't as necessary as some would have you believe. I tested weekly when I first started, but now am lucky to test every 3-4 months. I think that knowing your system is a better "daily check" of the parameters.

But as Jon said, testinng periodocally may circumvent the unexpected death of something due to a buildup of whatever. That is a good thing. (Back off Martha! )  

Anywho, I think that testing is actually a fun part of the hobby. Every so often, I get to go down into my dimly lit basement, put on my smock and nerd glasses (with the tape on the bridge) don my crazy grey hair wig and play mad scientist for an hour or so. (for some extra fun, conclude by exclaiming, "it's alive!.... IT'S ALIVE!!!!!! It keeps the neighbors guessing.)

In Syracuse

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Post Options Post Options   Thanks (0) Thanks(0)   Quote Adam Blundell Quote  Post ReplyReply Direct Link To This Post Posted: March 16 2004 at 9:48am

Keither, get this, I do have a minor in chem from the U, and I to had to sit through chem.  Gen chem was by far the best, be glad you didn't take that last class.

Okay, so Kris Fidone was in the biochem program at the U a few years back and he was making his own additives that he got from the Eyring Building's stock room.  I think?  He was also working up in R.P. so he may have gotten stuff there as well.  If I were you I would talk to him about making your own test kits.  If I remember correctly he had the same impression I had... it just wasn't worth the time and cost since you can go buy them.

Jon- there just fish and corals, you can always buy more. .  Okay so I'm kidding about that.  But hey, if you are doing water changes, then I still think testing is over-rated.

Adam

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Keither View Drop Down
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Post Options Post Options   Thanks (0) Thanks(0)   Quote Keither Quote  Post ReplyReply Direct Link To This Post Posted: March 16 2004 at 9:49am

I'm more of the non-tester myself.  Probably because it requires a lot of time when I'm strapped with school and work anyway.  I'm starting a 40 gallon soon, since Mark(Thank you!!) gave me some rock. I wanted to do this on the right way, but I to just watch things.  I just tested my small nano tank my friend traded me.  The specific weight of the water is high, but everything is great.  So I'm not going to mess with it.

:)

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Post Options Post Options   Thanks (0) Thanks(0)   Quote jfinch Quote  Post ReplyReply Direct Link To This Post Posted: March 16 2004 at 10:04am

O chem and Gen Chem were more interesting.

you sick sick puppy .  There's a cure for that you know?

I mean they only give you small bottles of everything, would it be a worthwhile venture to go and find some of the chems you need in somewhat larger quantities, instead of a couple of mils, I'd get a couple deci liters or something.

Well it's not the reagent chemicals that are the problem, it's the indicator solutions.  Many are proprietary.  For example, the calcium test kit uses two reagents.  The first is just 8N KOH, no big deal, easy to get.  The second is a standard solution of sodium EDTA, again fairly easy to get.  But the indicator dye is usually proprietary (and in the case of hobby test kits, the dye is mixed in with the EDTA).  I use off the shelf KOH and EDTA, but use a calcium indicator powder from HACH chemical.  The HACH product isn't exactly cheap.  In place of the HACH indicator you could use (I think) ektachrome T, but the color change is more difficult to see.  Anyway if you're really serious go search around the EPA website for their standard testing procedures.  They'll list all reagents needed and methods behind them.  Or look through your analytical chemistry text book, there are many procedures listed there too.  I've gone through the same thought processes you're going through and my conclusion was to just buy the test kits .  But you might find a different route .

Chemicals are expensive.  I've been pricing salts to make my own B-ionic and the costs are excessive ($150 for 400 g of SrCl2 !!).

I think that testing is actually a fun part of the hobby. Every so often, I get to go down into my dimly lit basement, put on my smock and nerd glasses (with the tape on the bridge) don my crazy grey hair wig and play mad scientist for an hour or so.

  Me too... oh wait, I do it for more then a couple hours at a time

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Post Options Post Options   Thanks (0) Thanks(0)   Quote jfinch Quote  Post ReplyReply Direct Link To This Post Posted: March 16 2004 at 10:09am

 But hey, if you are doing water changes, then I still think testing is over-rated.

I sometimes forget that there are folks who don't use any additives (calcium and alkalinity in particular).  In that case I agree completely.  If you don't use any additives and you do regular water changes then there's less of a need to test the water.

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